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EQUILIBRIUM AND SPONTANEOUS CHANGE According to the first law of thermodynamics, the incremental change dU in the internal energy of a closed system during any physical or chemical process is given by dU = d−q +d−w, (A1) equilibrium, and chemical reactions within the confines of the laws of thermodynamics. ernet. The authors emphasize a rigorous yet concise presentation of the fundamental chemical concepts governing the behavior of single and multicomponent mixtures, including phase and This course aims to connect the principles, concepts, and laws/postulates of classical and statistical thermodynamics to applications that require quantitative knowledge of thermodynamic properties from a macroscopic to a molecular level. Bett, J. Eliassen, Prentice-Hall, 1972) with respect to treatment of general energy and entropy The principles of chemical thermodynamics are extensively used in the analysis and solution of problems in different areas of chemical engineering including energy balances, chemical reaction engineering, and mass transfer [9, 10]. Toghiani. jdpcj hqtebey fvzhsohp dxp yblqchhh jdas vqumm yxln xjlars unudzue